682772-47-0Relevant articles and documents
Ring-closing metathesis for the synthesis of novel 9- and 10-membered silicon-containing benzo-fused heterocycles
Scalzullo, Stefania M.,Islam, Rafique Ul,Morgans, Garreth L.,Michael, Joseph P.,van Otterlo, Willem A.L.
scheme or table, p. 7403 - 7405 (2009/05/11)
A ring-closing metathesis (RCM) strategy afforded a number of novel 9- and 10-membered benzo-fused compounds containing at least one silicon atom as part of the heterocyclic portion. In this manner, the following compounds containing heterocyclic rings of 9-10 atoms were synthesized: (Z)-2,2-dimethyl-7-[(4-methylphenyl)sulfonyl]-2,3,6,7-tetrahydrobenzo[h][1,7,2]oxazasilonine, (Z)-2,2-dimethyl-3,6-dihydro-2H-benzo[h][1,7,2]dioxasilonine, (Z)-8-isopropoxy-9-methoxy-3,3-dimethyl-1,3,4,7-tetrahydrobenzo[g][1,2]oxasilonine and (Z)-2,2,7,7-tetramethyl-2,3,6,7-tetrahydrobenzo[i][1,8,2,7]dioxadisilecine.
Highly selective isomerization of allyloxyalcohols to cyclic acetals or 1-propenyloxyalcohols
Urbala, Magdalena,Ku?nik, Nikodem,Krompiec, Stanis?aw,Rzepa, Józef
, p. 1203 - 1206 (2007/10/03)
Highly selective isomerization of allyloxyalcohols either to 1-propenyl derivatives or to cyclic acetals of propanal depending on the transition metal (Ru, Rh) complex used is described together with a proposed explanation of an alternative reaction, which permits broad application of the described method.
Synthesis of 2H-1,5-benzodioxepin and 2,5-dihydro-1,6-benzodioxocin derivatives via ring-closing metathesis reaction
Mamouni,Soukri,Lazar,Akssira,Guillaumet
, p. 2631 - 2633 (2007/10/03)
The synthesis of various 2H-1,5-benzodioxepin and 2,5-dihydro-1,6- benzodioxocin derivatives is described. The key step involves the construction of seven- and eight-membered rings via ring-closing metathesis reaction.
