682807-99-4

Upstream product

• 34410-04-3 2-lithio-2-trimethylsilyl-1,3-dithiane 
• 682807-97-2 Trifluoro-methanesulfonic acid (2S,3S,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylmethyl ester 
• 113019-43-5 2,3,4,6-tetra-O-benzyl-1-formyl-D-glucopyranose 
• 89064-71-1 β-C-(hydroxymethyl)-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Synthesis of Fluorinated Homo-C-Nucleoside Analogues from New Carbohydrate-Derived Acylsilanes

Abstract: The stereocontrolled synthesis of new carbohydrate-derived acylsilanes with the silylcarbonyl moiety linked to the anomeric carbon via a methylene group is described. Reaction of these acylsilanes with perfluoroorganometallic reagents followed by treatment with hydrazines or amidines led to new polyfluorinated homo-C-nucleoside analogues, in a one-pot or two-step transformation, respectively.