68295-65-8Relevant academic research and scientific papers
Synthesis of optically active 1-alkoxysilacyclopentane derivatives
Miyakawa, Kenichi,Hamanishi, Eri,Arimitsu, Koji,Nagao, Yukinori
experimental part, p. 1617 - 1625 (2009/10/04)
The 1-chloro-2,5-dimethyl-l-phenyl-l-silacyclopentane was reacted with various optically active alcohols to give 1-alkoxysilacyclopentane derivatives, and some crystalline materials of the 1-alkoxysilacyclopentane derivatives could be separated from these
Optical Resolution and Absolute Stereochemistry of trans-2,5-Dimethyl-1-phenyl-1-silacyclopentane
Dang, Hai-Shan,Roberts, Brian P.,Tocher, Derek A.
, p. 117 - 124 (2007/10/02)
2,5-Dimethyl-1-phenyl-1-silacyclopentane (DMPSC) has been prepared in good yield, as a mixture of stereoisomers, by the reaction of 2,5-dibromohexane and dichlorophenylsilane with magnesium in tetrahydrofuran.The silane so prepared consists of a ca. 1:1.3
