6833-23-4

Basic information

• Product Name: 3-METHOXY-N-PHENYLBENZAMIDE
• Synonyms: 3-METHOXY-N-PHENYLBENZAMIDE;3-Methoxybenzanilide;M-Anisanilide;N-Phenyl-3-MethoxybenzaMide;N-Phenyl-M-anisaMide
• CAS NO: 6833-23-4
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.26
• Product Categories: Aromatics Compounds;Aromatics
• Mol File: 6833-23-4.mol
• Article Data: 46

Chemical Properties

• Melting Point: 114-116°C
• Appearance: /
• Storage Temp.: Refrigerator
• Solubility: Chloroform, Methanol
• CAS DataBase Reference: 3-METHOXY-N-PHENYLBENZAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHOXY-N-PHENYLBENZAMIDE(6833-23-4)
• EPA Substance Registry System: 3-METHOXY-N-PHENYLBENZAMIDE(6833-23-4)

Safety Data

• Hazardous Substances Data: 6833-23-4(Hazardous Substances Data)

Usage

Chemical Properties

Light Pink Solid

Uses

3-Methoxy-N-phenylbenzamide (cas# 6833-23-4) is a compound useful in organic synthesis.

Upstream product

• 119870-87-0 3-methoxybenzophenone 4-methylphenylsulfonylhydrazone 
• 6971-51-3 3-methoxybenzyl alcohol 
• 62-53-3 aniline 
• 103-71-9 phenyl isocyanate 
• 100-09-4 4-methoxybenzoic acid 
• 579-75-9 2-Methoxybenzoic acid 
• 5000-65-7 2-bromo-3'-methoxyacetophenone 
• 201230-82-2 carbon monoxide 
• 35692-26-3 3-trimethoxyphenyltrimethoxysilane 
• 10259-22-0 ethyl 3-methoxybenzoate 
• 87281-97-8 3-Methoxy-N-phenyl-benzimidoyl chloride 
• 10365-98-7 3-methoxyphenylboronic acid 
• 425365-97-5 3-methoxy-N-phenyl-benzimidic acid 4-cyano-phenyl ester 
• 425366-14-9 (3-methoxy-phenylmethylidyne)-phenyl-ammonium 

Downstream Products

• 77305-99-8 C₁₄H₁₁LiNO₂^(1-)*Li⁽¹⁺⁾ 
• 95068-31-8 3-(2-Methoxyphenyl)-4-methoxy-3H-isobenzofuran-1-one 
• 87281-97-8 3-Methoxy-N-phenyl-benzimidoyl chloride 
• 1457958-23-4 N,N'-diphenyl-3-methoxybenzamidine 
• 27559-45-1 3-hydroxy-N-phenyl-benzamide 
• 154822-34-1 3-hydroxy-4-methoxy-2-phenyl-3-(4-pyridyl)-2,3-dihydro-1H-isoindolin-1-one 
• 154822-30-7 3-hydroxy-4-methoxy-2-phenyl-3-(2-pyridyl)-2,3-dihydro-1H-isoindolin-1-one 
• 147637-15-8 3-hydroxy-4-methoxy-2-phenyl-2,3-dihydro-1H-isoindol-1-one 
• 81744-28-7 3-Methoxy-2-methylselanyl-N-phenyl-benzamide 
• 5892-84-2 (3-Methoxy-benzoyl)-phenyl-carbamic acid isopropyl ester 

Relevant articles and documents

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Chromium-catalyzed ligand-free amidation of esters with anilines

Amides are important structural motifs in pharmaceutical and agrochemical chemistry because of the intriguing biological active properties. We report here the amidation of commercially available esters with anilines that was promoted by low-cost and air-stable chromium(III) pre-catalyst combined with magnesium, providing access to amides. This reaction occurs without the use of external ligands in a simple operation. Mechanistic studies indicate that a reactive aminated Cr species responsible for the amidation can be considered, which may be formed by reaction of low-valent Cr with aniline followed by reduction with hydrogen evolution.

Visible-Light-Promoted Iron-Catalyzed N-Arylation of Dioxazolones with Arylboronic Acids

A visible-light-promoted and simple iron salt-catalyzed N-arylation was achieved efficiently under external photosensitizer-free conditions. Arylboronic acids and bench-stable dioxazolones were used for this cross-coupling reaction. This reaction features high reactivity, wide substrate scope, good functional group tolerance, simple operation procedure, and mild reaction conditions. Preliminary mechanistic investigations were conducted to support a radical pathway. This method may contribute to shift the paradigm of iron-catalyzed C-N bond construction and nitrene transfer chemistry.