68376-08-9

Basic information

• Product Name: Methanone, phenyl(3-phenyl-2-naphthalenyl)-
• CAS NO: 68376-08-9
• Molecular Formula: C23H16O
• Molecular Weight: 308.379
• Mol File: 68376-08-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Methanone, phenyl(3-phenyl-2-naphthalenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, phenyl(3-phenyl-2-naphthalenyl)-(68376-08-9)
• EPA Substance Registry System: Methanone, phenyl(3-phenyl-2-naphthalenyl)-(68376-08-9)

Safety Data

• Hazardous Substances Data: 68376-08-9(Hazardous Substances Data)

Upstream product

• 612-12-4 o-Xylylene dichloride 
• 120-46-7 1,3-diphenylpropanedione 
• 26260-02-6 2-iodobenzaldehyde 
• 1436869-06-5 1,3-diphenylcyclobut-2-enol 
• 98-80-6 phenylboronic acid 
• 28215-42-1 (3-hydroxy-naphthalen-2-yl)-phenyl-methanone 
• 1393090-01-1 tert-butyl 3-phenyl-1-(2-(phenylethynyl)phenyl)prop-2-ynyl carbonate 

Relevant articles and documents

Palladium-Catalyzed Ring-Opening Coupling of Cyclobutenols with Aryl Halides

A palladium(0)-catalyzed ring-opening cross-coupling reaction between tert -cyclobutenols and aryl halides produces γ-arylated β,γ-unsaturated ketones. In the case of aryl halides bearing functional groups at the ortho position, the resulting ring-opened ketones undergo intramolecular condensation to afford bicyclic aromatic compounds.

Synthesis of Polysubstituted 2-Naphthols by Palladium-Catalyzed Intramolecular Arylation/Aromatization Cascade

A palladium-catalyzed intramolecular α-arylation and defluorinative aromatization strategy for the synthesis of polysubstituted 2-naphthols is reported. With ortho-bromobenzyl-substituted α-fluoroketones as the substrates and palladium acetate/triphenylphosphine as the catalyst, this method features good functional group tolerance, readily available catalyst and starting materials, and high yields. The applications of the strategy are demonstrated by the synthesis of useful building blocks, such as naphtha[2,3-b]furan, naphthol AS-D, and ligands/catalysts. (Figure presented.).

Generation of o-quinodimethanes (o-QDMs) from benzo[c]oxepines and the synthetic application for polysubstituted tetrahydronaphthalenes

A novel method for the generation of o-quinodimethane (o-QDM) intermediates is reported using a mild and efficient base-promoted ring-opening of benzo[c]oxepines. Among the benzo[c]oxepines studied, indanone containing analogues demonstrated the greatest