68376-31-8

Basic information

• Product Name: (phenyl)[2-(tosylmethyl)phenyl]methanone
• Synonyms: (phenyl)[2-(tosylmethyl)phenyl]methanone
• CAS NO: 68376-31-8
• Molecular Weight: 350.438
• Mol File: 68376-31-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (phenyl)[2-(tosylmethyl)phenyl]methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (phenyl)[2-(tosylmethyl)phenyl]methanone(68376-31-8)
• EPA Substance Registry System: (phenyl)[2-(tosylmethyl)phenyl]methanone(68376-31-8)

Safety Data

• Hazardous Substances Data: 68376-31-8(Hazardous Substances Data)

Upstream product

• 131-58-8 2-Methylbenzophenone 
• 98-59-9 p-toluenesulfonyl chloride 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 611-73-4 Benzoylformic acid 
• 5023-60-9 1-benzylsulfanyl-4-methyl-benzene 
• 31378-03-7 1-phenyl-2-tosylethanone 

Relevant articles and documents

A novel multicomponent reaction of arynes, β-keto sulfones, and Michael-type acceptors: A direct synthesis of polysubstituted naphthols and naphthalenes

(Chemical Equation Presented) A novel multicomponent reaction of arynes, β-keto sulfones, and Michael-type acceptors is presented, providing an efficient method for the synthesis of polysubstituted naphthols and polysubstituted naphthalenes. Further investigation suggests that the tandem reaction may proceed via a sequential nucleophilic attack to arynes, intramolecular nucleophilic substitution followed by a Michael addition, and a ring closure - elimination process.

Palladium-catalyzed C-H acylation of arenes using thioethers as directing groups

A highly efficient protocol for regioselective synthesis of diaryl ketones by palladium-catalyzed direct acylation of arenes using thioethers as directing groups is reported. The possible pathway of direct acylation between thioethers and α-oxocarboxylic acids is discussed. The direct acylation of thioethers via Pd-catalyzed C-H bond activation was described. Copyright