6839-10-7

Usage

Physical state

White solid

Aroma

Floral, sweet

Common uses

Production of perfumes, soaps, and cosmetics

Additional uses

Fragrance in personal care products, flavoring agent in the food industry

Toxicity

Low toxicity, generally considered safe for use in consumer products when used as directed

Upstream product

• 135-02-4 ortho-anisaldehyde 
• 703-55-9 1-naphthylmagnesiumbromide 
• 13922-41-3 1-Naphthylboronic acid 
• 18052-80-7 1-naphthyltrimethylsilane 

Downstream Products

• 6839-17-4 bis-[(2-methoxy-phenyl)-[1]naphthyl-methyl]-ether 

Relevant academic research and scientific papers

Bis(2-alkylpyrrolidin-1-yl)methylidenes as chiral acyclic diaminocarbene ligands

2-Alkylpyrrolidines were used as building blocks for acyclic diaminocarbenes (ADCs). First, ureas were made from the corresponding amines, and then the ureas were converted to chloroamidiniums. The chloroamidiniums served as direct precursors to ADCs, and

A new route to acyclic diaminocarbenes via lithium-halogen exchange

A lithium - halogen exchange route has been developed to generate acyclic diaminocarbenes (ADC) from chloroamidinium salts. Convenient access to various ADC complexes (B, Rh, lr, Pd) stems from a one-pot transmetalation protocol. Formation of a carbenoid species is suggested by 1D and 2D NMR studies with a 13C-labeled chloroamidinium precursor and also by X-ray structures of transition metal-carbene complexes. Rh-ADC complex 4 is an effective catalyst for the 1,2-addition of aryl boronic acids to aryl aldehydes.

Phosphazene base-promoted functionalization of aryltrimethylsilanes

The activation of Ar-Si bonds in aryltrimethylsilane was investigated using a catalytic amount of t-Bu-P4 base and selective functionalizations of aryltrimethylsilanes in the absence of strong electron withdrawing groups on the aromatic rings were accomplished. The Royal Society of Chemistry 2006.