68457-27-2Relevant academic research and scientific papers
Addition of Water to o-Phenylethinyl-substituted Triphenylphosphanes and Reduction of the Formed Phosphane Oxide En-ynes
Butters, Thomas,Haller-Pauls, Irene,Winter, Werner
, p. 578 - 592 (2007/10/02)
Heating of the o-phenylethinyl-substituted triphenylphosphanes 1a - c in organic solvents containing water affords the phosphane oxides 2a - c through an intramolecular nucleophilic addition of the phosphorus to the triple bond, stereoselectively with a t
