68461-02-9

Upstream product

• 68460-95-7 N-allyl-2-ethylaniline 
• 578-54-1 ortho-ethylaniline 

Downstream Products

• 68460-62-8 [(2-Allyl-6-ethyl-phenyl)-(2-chloro-acetyl)-amino]-acetic acid butyl ester 
• 1309578-79-7 N-(2-allyl-6-ethylphenyl)-4-methylbenzenesulfonamide 
• 1309579-00-7 methyl 2-(7-ethyl-1-tosylindolin-2-yl)acetate 
• 1309578-50-4 (E)-methyl 4-(3-ethyl-2-(4-methylphenylsulfonamido)phenyl)but-2-enoate 
• 68460-60-6 N-(2-Allyl-6-ethyl-phenyl)-N-butoxymethyl-2-chloro-acetamide 
• 68460-61-7 N-(2-Allyl-6-ethyl-phenyl)-2-chloro-N-isopropoxymethyl-acetamide 
• 68460-87-7 N-Butoxymethyl-2-chloro-N-[2-ethyl-6-((E)-propenyl)-phenyl]-acetamide 
• 68460-86-6 2-Chloro-N-[2-ethyl-6-((E)-propenyl)-phenyl]-N-isopropoxymethyl-acetamide 
• 68460-85-5 2-Chloro-N-[2-ethyl-6-((E)-propenyl)-phenyl]-N-methoxymethyl-acetamide 
• 911294-85-4 N-(2-allyl-6-ethylphenyl)benzamide 
• 68461-09-6 2-Ethyl-6-propenylanilin 
• 68460-98-0 N-Methylen-2-ethyl-6-(2'-propenyl)anilin 

Relevant academic research and scientific papers

Synthesis of Benzofuran and Indole Derivatives Catalyzed by Palladium on Carbon

Benzofurans and indoles are key moieties in many natural products and pharmaceuticals. Herein, we describe a cheap and easy-to-execute strategy for the synthesis of benzofurans and indoles, employing Pd/C as the promoter. A variety of substituted allyl-anilines and allyl-phenols were converted into the desired products in good to excellent yields. Recycling of Pd/C was possible up to five cycles, keeping similar levels of reactivity.

Green Organocatalytic Synthesis of Indolines and Pyrrolidines from Alkenes

Employing a green and efficient 2,2,2-trifluoroacetophenone-catalyzed oxidation of alkenes, which utilizes H2O2 as the green oxidant, a novel and sustainable synthesis of indolines and pyrrolidines was developed. This constitutes a cheap, general and environmentally-friendly protocol for the synthesis of substituted nitrogen-containing heterocycles. A variety of substitution patterns, both aromatic and aliphatic moieties, are well tolerated leading to the desired nitrogen heterocycles in good to excellent yields. (Figure presented.).

A metal-free approach to the synthesis of indoline derivatives by a phenyliodine(III) bis(trifluoroacetate)-mediated amidohydroxylation reaction

A novel approach to the synthesis of indoline derivatives is presented. The key cyclization step features the phenyliodine-(III) bis(trifluoroacetate)- (PIFA-) mediated formation of a N-acylnitrenium ion and its succeeding intramolecular trapping by the o

Chloroacetanilides having a selective herbicidal activity, ortho-alkenyl-substituted anilines, intermediates in the synthesis of said herbicidal chloroacetanilides, and methods for their preparation

Chloroacetanilides are disclosed having the general formula: STR1 wherein R1 =H, or alkyl with 1-5 carbon atoms, or X; X=alkenyl, and preferably STR2 in which the various R2, which may be equal to or different from each other, are H