68469-61-4Relevant academic research and scientific papers
Copper-catalyzed arylation of chlorosilanes with grignard reagents
Morita, Eiji,Murakami, Kei,Iwasaki, Masayuki,Hirano, Koji,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 1012 - 1014 (2011/02/26)
Nucleophilic substitution reactions of chlorosilanes with aryl Grignard reagents take place efficiently in the presence of copper(I) iodide to afford tetraorganosilanes.
Silver-catalyzed transmetalation between chlorosilanes and aryl and alkenyl Grignard reagents for the synthesis of tetraorganosilanes
Murakami, Kei,Hirano, Koji,Yorimitsu, Hideki,Oshima, Koichiro
supporting information; scheme or table, p. 5833 - 5835 (2009/03/11)
(Chemical Equation Presented) The silver savior: Nucleophilic substitution reactions of chlorosilanes with aryl Grignard reagents have been developed which take place under silver catalysis to afford tetraorganosilanes (see scheme). This transformation is likely to be promoted by diarylargentate reagents that are generated in situ.
