68469-77-2

Upstream product

• 109-04-6 2-bromo-pyridine 
• 68469-71-6 2,2'-(phenylphosphanediyl)dipyridine 

Downstream Products

• 366-18-7 [2,2]bipyridinyl 
• 110-86-1 pyridine 
• 101-82-6 2-Benzylpyridine 
• 4350-41-8 2-(4-chlorobenzyl)pyridine 
• 15550-00-2 cis-[RhCl₂(CO)2]^(1-) 
• 329768-34-5 [Rh(CO)2((NC₅H₄)2P(O)C₆H₅)]⁽¹⁺⁾ 
• 184651-00-1 fac-[Mo(CO)3(bis(2-pyridyl)phenylphosphine oxide-N₂,O)] 
• 280767-98-8 [Mo(CH₂CHCH₂)Br(CO)2(OP(C₅H₄N)2C₆H₅)] 
• 329768-35-6 [Rh(CO)2((NC₅H₄)2P(O)C₆H₅)]⁽¹⁺⁾*BF₄^(1-) = [Rh(CO)2((NC₅H₄)2P(O)C₆H₅)]BF₄ 
• 329768-33-4 [Rh(C(CF)4C(CH)6)((NC₅H₄)2P(O)C₆H₅)]⁽¹⁺⁾*BF₄^(1-) = [Rh(C(CF)4C(CH)6)((NC₅H₄)2P(O)C₆H₅)]BF₄ 
• 329768-31-2 [Rh(C₈H₁₂)((NC₅H₄)2P(O)C₆H₅)]⁽¹⁺⁾*BF₄^(1-) = [Rh(C₈H₁₂)((NC₅H₄)2P(O)C₆H₅)]BF₄ 
• 329768-43-6 [Rh(CO)2((NC₅H₄)2P(O)C₆H₅)]⁽¹⁺⁾*RhCl₂(CO)2^(1-) = [Rh(CO)2((NC₅H₄)2P(O)C₆H₅)][RhCl₂(CO)2] 
• 801319-73-3 [Pd(2,4,6-tris(trifluoromethyl)phenyl)2(κ2O,N-OP(C6H5)(C5H4N)2)] 
• 910578-94-8 [Pd(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)(OPPhPy₂-N,N')][BF₄] 

Relevant academic research and scientific papers

Transition Metal Complexes with Tripodal Ligands and the Use Thereof in OLEDs

The present invention relates to metal complexes of the general formula L1ML2 (I), wherein M is selected from Ir and Rh,L1 is a ligand of formula L2 is a ligand of formula to OLEDs (Organic Light-Emitting Diodes

Nitrogenous heterocyclic phosphoric acid and preparation method thereof, and luminescent device using nitrogenous heterocyclic phosphoric acid

The invention relates to a compound with a nitrogenous heterocyclic phosphoric acid structure. The compound can be used as a metal ligand for preparation of an organic luminescent material. Compared with extensively researched and reported phosphoric acid ligand, the novel nitrogenous heterocyclic phosphoric acid ligand provided by the invention has the advantages of stable chemical properties, easiness in purification, etc. and can effectively regulate the luminescence color of a metal complex due to introduction of a heavy electron phosphoric acid coordination structure. Through modification of the molecular structure of substituent on a nitrogenous heterocyclic ring, the luminescence position of the complex can be adjusted in the range of blue light wavelength, which facilitates designing and production of organic electroluminescence displays and illumination light sources. Moreover, the invention provides a synthetic method for a series of novel nitrogenous heterocyclic phosphoric acids. The synthetic method is simple, has high yield and realizes flexible chemical modification of heterocycles.