685077-49-0

Basic information

• Product Name: (1S,2S,4R,9R)-4-[4-(tert-butyldiphenylsilyloxy)butyl]-9-hydroxy-4,8,11,11-tetramethyl-2-(phenylmethoxy)bicyclo[5.3.1]undec-7-en-3-one
• Synonyms: (1S,2S,4R,9R)-4-[4-(tert-butyldiphenylsilyloxy)butyl]-9-hydroxy-4,8,11,11-tetramethyl-2-(phenylmethoxy)bicyclo[5.3.1]undec-7-en-3-one
• CAS NO: 685077-49-0
• Molecular Weight: 652.99
• Mol File: 685077-49-0.mol

Chemical Properties

• CAS DataBase Reference: (1S,2S,4R,9R)-4-[4-(tert-butyldiphenylsilyloxy)butyl]-9-hydroxy-4,8,11,11-tetramethyl-2-(phenylmethoxy)bicyclo[5.3.1]undec-7-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S,4R,9R)-4-[4-(tert-butyldiphenylsilyloxy)butyl]-9-hydroxy-4,8,11,11-tetramethyl-2-(phenylmethoxy)bicyclo[5.3.1]undec-7-en-3-one(685077-49-0)
• EPA Substance Registry System: (1S,2S,4R,9R)-4-[4-(tert-butyldiphenylsilyloxy)butyl]-9-hydroxy-4,8,11,11-tetramethyl-2-(phenylmethoxy)bicyclo[5.3.1]undec-7-en-3-one(685077-49-0)

Safety Data

• Hazardous Substances Data: 685077-49-0(Hazardous Substances Data)

Upstream product

• 685077-48-9 (1R,3aR,7S,8S,8aR)-1-[4-(tert-butyldiphenylsilyloxy)butyl]-2,3,7,8-tetrahydro-1,4,9,9-tetramethyl-8-(phenylmethoxy)-1H-3a,7-methanoazulen-8a(6H)-ol 

Downstream Products

• 685077-56-9 (1S,2S,4R)-4-(4-hydroxybutyl)-4,8,11,11-tetramethyl-2-(phenylmethoxy)bicyclo[5.3.1]undec-7-ene-3,9-dione 
• 685077-57-0 (1S,2S,4R)-4-(4-bromobutyl)-4,8,11,11-tetramethyl-2-(phenylmethoxy)bicyclo[5.3.1]undec-7-ene-3,9-dione 

Relevant articles and documents

Taxane diterpene synthesis studies. Part 2: Towards taxinine - enantiospecific construction of an AB-ring substructure incorporating both quaternary carbon centres and attempts to annulate the C-ring

In connection with efforts to develop an efficient total synthesis of the biologically active natural product taxinine 1, the enzymatically-derived and monochiral cis-1,2-dihydrocatechol 7 was converted, over several steps including a Diels-Alder cycloadd