685142-69-2

Upstream product

• 1779-49-3 Methyltriphenylphosphonium bromide 
• 685142-68-1 (2S,4R,5R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-5-methoxy-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-carbaldehyde 
• 35781-73-8 (-)-(3aR,5R,6aR)-methyl 3a,5,6,6a-tetrahydro-2,2-dimethylfuro[2,3-d][1,3]dioxole-5-carboxylate 
• 2946-01-2 (3aR,5R,6S,6aR)-5-((R)-1,2-dihydroxyethyl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-yl 4-methylbenzenesulfonate 
• 685142-64-7 (-)-(2R,4R,5R)-methyl 4-(4-methoxybenzyloxy)-5-methoxytetrahydrofuran-2-carboxylate 
• 685142-75-0 (2S,4R,5R)-methyl 4-(4-methoxybenzyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-5-methoxytetrahydrofuran-2-carboxylate 
• 1033126-30-5 C₂₄H₃₂O₄Si 
• 2746-25-0 p-Methoxybenzyl bromide 
• 685142-66-9 (2S,4R,5R)-2-Hydroxymethyl-5-methoxy-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-carboxylic acid methyl ester 

Downstream Products

• 685142-72-7 (-)-(1S,2R,4R)-4-(4-methoxybenzyloxy)-2-(tert-butyldiphenylsiloxymethyl)-2-vinylcyclobutanol 
• 1033126-32-7 (+)-(1R,2S,4R)-4-(4-methoxybenzyloxy)-2-(tert-butyldiphenylsiloxymethyl)-2-vinylcyclobutanol 

Relevant academic research and scientific papers

The carbohydrate-sesquiterpene interface. Directed synthetic routes to both (+)- and (-)-fomannosin from D-glucose

(Chemical Equation Presented) An enantiodivergent strategy for the total chemical synthesis of both naturally occurring (+)-fomannosin (1) and its (-)-antipode (ent-1) from α-D-glucose has been developed and successfully implemented. The key steps in the

Synthesis of an enantiomerically pure 2,2,4-trisubstituted cyclobutanone building block by zirconocene-promoted deoxygenative ring contraction of structurally modified 4-vinylfuranosides

A route to an enantiopure trisubstituted cyclobutanone has been devised. The pursuit of this building block begins with D-glucose and features a zirconocene-promoted ring contraction.