68558-92-9Relevant academic research and scientific papers
Conversion of Vinylsilanes in the Presence of Triethoxysilane Catalyzed by Ruthenium Complexes
Gulinski, J.
, p. 1266 - 1272 (2007/10/02)
Reaction of vinylsilanes with triethoxysilane catalyzed by ruthenium phosphine and non-phosphine complexes proceed via several competitive-consecutive routes including hydrosilylation, metathesis, hydrogenation and dehydrogenative silylation as well as migration and oxygenation of silyl groups, ethene hydrosilylation and catalytic redistribution of triethoxysilane.Ruthenium hydride and/or ruthenium silyl complexes seem to play the role of key intermediates in all the processes mentioned above.Key words: ruthenium complexes, silyl complexes, hydride complexes, competitive-consecutive reaction
