6857-06-3Relevant academic research and scientific papers
REACTION OF N,N'-DIAROYLSULFUR DIIMIDES WITH OLEFINS
Barashenkov, G. G.,Derkach, N. Ya.,Levchenko, E. S.,Kalinin, V. N.
, p. 468 - 473 (2007/10/02)
N,N'-Diaroylsulfur diimides react with olefins by a mechanism of the -cycloaddition type with the formation of 2-aryl-4-aroylimino-5,6-dihydro-4,1,3-thiaoxazines.The latter are converted by the action of bases into the N,N'-diaroylamidines of unsatur
DERIVATIVES OF SULFOXYLIC DIAMIDE
Pel'kis, N. P.,Levchenko, E. S.
, p. 1963 - 1967 (2007/10/02)
N,N'-Disubstituted sulfur diimides are reduced by the action of thiophenols to N,N'-disubstituted sulfoxylic diamides R1NHSNHR2.Compounds where R1 = R2 = SO2Ar, COPh enter readily into reaction both with retention and with cleavage of the S-N bond.In reaction with secondary amines and CH acids they are "carriers of sulfur." 2,5-Diaroyl-1,2,5-thiadiazolidine-3,4-diones are formed by the successive action of trimethylchlorosilane and oxalyl chloride on the compounds where R1 = R2 = COPh, COC6H4Cl-p.
