685876-54-4Relevant academic research and scientific papers
Oxidation-state and metal-ion dependent stereoisomerization in oxo molybdenum and tungsten complexes of a bulky alkoxy heteroscorpionate ligand
Hoffman, Justin T.,Tran, Ba L.,Carrano, Carl J.
, p. 3822 - 3830 (2006)
Monooxo Mo(V) complexes of a N2O heteroscorpionate ligand designated (L10O) are found to exist as isolable cis and trans isomers. We have been able to trap the kinetically labile cis isomer and follow its isomerization to the thermodynamically
Synthesis and characterization of heteroscorpionate rare-earth metal dialkyl complexes and catalysis on MMA polymerization
Zhang, Zhichao,Cui, Dongmei,Trifonov, Alexander A.
experimental part, p. 2861 - 2866 (2010/10/02)
A series of rare-earth metal alkyl complexes supported by a heteroscorpionate ligand were prepared and structurally characterized. X-ray diffraction analysis revealed that the heteroscorpionate ligand is face-capping on the rare-earth metal in k3/su
