68688-02-8Relevant academic research and scientific papers
Stereoselective Synthesis of Alcohols, I Synthesis of One-Carbon Homologous Allyl Alcohols from Aldehydes or Ketones
Hoffmann, Reinhard W.,Goldmann, Siegfried,Maak, Norbert,Gerlach, Rainer,Frickel, Fritz,Steinbach, Gertrud
, p. 819 - 830 (2007/10/02)
The high yield conversion of aldehydes and ketones 2 to the one-carbon homologous allyl alcohols 3 is achieved by condensation to the vinyl sulfoxides 7, isomerisation to the allyl sulfoxides 9, and subsequent sigmatropic rearrangement.
