68705-88-4Relevant academic research and scientific papers
Surprisingly efficient catalytic Cr-mediated coupling reactions
Namba, Kosuke,Wang, Jiashi,Cui, Sheng,Kishi, Yoshito
, p. 5421 - 5424 (2007/10/03)
(Chemical Equation Presented) With use of 1 mol % of Cr catalyst 5, surprisingly efficient Cr-mediated couplings of aldehydes with various types of nucleophiles have been realized. The catalyst set of Cr catalyst 5 and Ni catalyst 4 is used for alkenylati
New and stereoselective synthesis of 1,4-disubstituted buten-4-ols (homoallylic alcohol α-adducts) from the corresponding γ-isomers (3,4-disubstituted buten-4-ols) via an acid-catalyzed allyl-transfer reaction with aldehydes
Sumida, Shin-Ichi,Ohga, Masanori,Mitani, Junji,Nokami, Junzo
, p. 1310 - 1313 (2007/10/03)
The γ-adducts of homoallylic alcohols 3, derived from aldehydes via the usual reaction with common allylic metals 1, were converted to the corresponding α-adducts 6 by an acid-catalyzed allyl-transfer reaction. In the allyl-transfer reaction, anti-and syn
