68748-95-8Relevant academic research and scientific papers
Phosphorylation of Adamantane and its Derivatives in Trifluoroacetic Acid Medium
Shokova,Erokhin,Kovalev
, p. 1624 - 1634 (2007/10/03)
The possibility of dichlorophosphorylation of the carcass compounds of the adamantane series and of aryl(alkyl)carbinols, with phosphorus trichloride in the low-nucleophilicity trifluoroacetic acid medium was first demonstrated. A new preparative method for introducing a POCl2 group into the bridgehead and bridge positions of the adamantane nucleus, as well as into the α position of the side chain was developed. Some intermediate adamantyl cations may undergo isometizations, among them skeleton ones. A mechanism of the phosphorylation was proposed.
Hypobetalipoproteinemic agents. II. Compounds related to 4-(1- adamantyloxy)aniline
Lednicer,Heyd,Emmert,et al.
, p. 69 - 77 (2007/10/06)
While the previously used displacement reaction of sodium 1-adamantyl oxide on 4-fluoronitrobenzene was applicable to the preparation of 4-(1-adamantyloxy) aniline and several related compounds, certain derivatives were not easily accessible by this route
