68759-08-0Relevant articles and documents
Megastigmane glycosides from seeds of Trifolium alexandrinum
Mohamed, Khaled M.,Mohamed, Mahmoud H.,Ohtani, Kazuhiro,Kasai, Ryoji,Yamasaki, Kazuo
, p. 859 - 862 (1999)
Five megastigmane glycosides have been isolated from the seeds of Trifolium alexandrinum L., of which two are known compounds, while three are new compounds showing the presence of apiofuranosyl-(1→2)-glucopyranosyl residue as a sugar moiety. The structures of the isolated compounds were established on the basis of NMR and mass spectral data.
Enantiocontrolled access to the ionone type bisnorsesquiterpenes. Total syntheses of 3-oxo-α-ionol and related natural products
Kikuchi, Daisuke,Yoshida, Masahiro,Shishido, Kozo
, p. 145 - 147 (2012/01/17)
The enantiocontrolled total syntheses of three ionone type bisnorsesquiterpenes have been accomplished employing a highly diastereoselective intramolecular Heck reaction as the key step.
TWO DIASTEREOMERIC 3-OXO-α-IONOL β-D-GLUCOSIDES FROM RASPBERRY FRUIT
Pabst, Anni,Barron, Denis,Semon, Etienne,Schreier, Peter
, p. 1649 - 1652 (2007/10/02)
From a methanolic extract of raspberry fruit two 3'-O-β-D-glucopyranosides of diastereomeric 4-(3'-hydroxy-1'-butenyl)-3,3,5-trimethyl-2-cyclohexen-1-one (3-oxo-α-ionol) were isolated by adsorption chromatography on XAD-2 followed by LC on Sephadex LH-20,
