688010-04-0Relevant academic research and scientific papers
Selective photochemical cleavage of an α-ketoamide in a highly functionalised macrolide ascomycin
Bulusu, Murty A.R.C.,Waldst?tten, Peter,Tricotett, Thomas,Schulz, Gerhard
, p. 2527 - 2530 (2004)
A novel photochemical amide cleavage reaction of (6S)-methoxyascomycin opening a pathway for the selective cleavage of the pipecolic acid, is described. The scope of this reaction with several analogues carrying suitable protecting groups is examined.
