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Similarity and Differences in the Regioselectivities of Thermal and Acid-Catalyzed van Alphen–Hüttel Rearrangements in the Series of 3,3-Diphenyl-3H-pyrazoles Containing Electron-Withdrawing Substituents on C4 and C5
Vasin,Razin,Bezrukova
, p. 1045 - 1054 (2018)
3,3-Diphenyl-3H-pyrazoles containing an electron-withdrawing substituent in the 5-position undergo van Alphen–Hüttel rearrangement with migration of one phenyl group to C4 on heating in an aprotic solvent (benzene, toluene), as well as on keepi
