68866-62-6Relevant articles and documents
Heteronuclear triangular clusters of the type [Pt2M(μ3-η1:η1:η 2-PhC≡CC≡CPh)(CO)5(PPh3) 2] (M= Fe or Ru)
Yamazaki, Shinsaku,Deeming, Antony J.,Speel, Despo M.
, p. 775 - 778 (1998)
The 46-electron heteronuclear clusters [Pt2M-(μ3-η1:η 1:η2-PhC≡CC≡CPh)(CO)5(PPh 3)2] (M = Fe or Ru) are formed in moderate yield by treating [Pt(η2-PhC≡ CC≡CPh)(PPh3)2] with [Fe(CO)5] or [Ru3(CO)12] in refluxing toluene. The Pt2Fe and Pt2Ru clusters are isostructural, being composed of two Pt(CO)(PPh3) units and a M(CO)3 group linked by two Pt-Fe or Pt-Ru bonds with the μ3-diyne coordinated through only one C≡C bond.