68884-32-2

Basic information

• Product Name: 1-Naphthylpropylene oxide
• Synonyms: 1-Naphthylpropylene oxide
• CAS NO: 68884-32-2
• Molecular Formula: C₁₃H₁₂O
• Molecular Weight: 184.23378
• Mol File: 68884-32-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 322.4°Cat760mmHg
• Flash Point: 143.8°C
• Appearance: /
• Density: 1.175g/cm³
• Vapor Pressure: 0.000528mmHg at 25°C
• Refractive Index: 1.659
• CAS DataBase Reference: 1-Naphthylpropylene oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Naphthylpropylene oxide(68884-32-2)
• EPA Substance Registry System: 1-Naphthylpropylene oxide(68884-32-2)

Safety Data

• Hazardous Substances Data: 68884-32-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H12O/c1-2-7-13-10(4-1)5-3-6-11(13)8-12-9-14-12/h1-7,12H,8-9H2

Upstream product

• 90-11-9 1-Bromonaphthalene 
• 703-55-9 1-naphthylmagnesiumbromide 
• 120727-54-0 1-chloro-3-[1]naphthyl-propan-2-ol 
• 2489-86-3 1-allylnaphthalene 

Downstream Products

• 2489-86-3 1-allylnaphthalene 
• 27653-22-1 3-(Naphth-1-yl)propan-1-ol 
• 145771-05-7 2-hydroxy-3-(1-naphthyl)-1-[1-(4-phenylpiperidinyl)]propane 

Relevant articles and documents

Stereospecific Deoxygenation of Aliphatic Epoxides to Alkenes under Rhenium Catalysis

The combination of a catalytic amount of Re2O7 and triphenyl phosphite as a reductant is effective for the deoxygenation of unactivated aliphatic epoxides to alkenes. The reaction proceeds stereospecifically with variously substituted epoxides under neutral conditions and is compatible with various functional groups. Protection and deprotection of a double bond functionality using an epoxide are shown as an example of the current rhenium-catalyzed deoxygenation protocol. The effect of reductants for the stereoselectivity has also been studied, indicating that the use of electron-deficient phosphines or phosphites is the key for the stereospecific deoxygenation. (Chemical Equation Presented).

Synthesis and study of the lubricating properties of some thiiranes

A series of novel thiiranes were synthesized, and their lubricating properties were studied. It has been found that they improve the antiscuff and antiwear properties of gear oils and therefore can be used as additives. The relation between the structure of the synthesized thiiranes and their lubricating activity was revealed.