68886-18-0Relevant academic research and scientific papers
Deltacyclene formation catalysed by cationic Co(II) complexes
Binger, P.,Albus, S.
, p. C6 - C8 (1995)
Alkynes and norbornadiene can be codimerized in a Homo-Diels-Alder reaction, yielding deltacyclenes.Instead of reduced Co species as used in former cases, Co(II)-complexes activated with Lewis acids such as ZnI2 or ZnCl2 are used to obtain the sam
Asymmetrische Katalysen LXX. Die hochenantioselektive Co-katalysierte Homo-Diels-Alder-Reaktion von Norbornadien mit Acetylenen
Brunner, Henri,Prester, Franz
, p. 401 - 409 (2007/10/02)
The enantioselective homo Diels-Alder reaction of norbornadiene with monosubstituted acetylenes affords optically active deltacyclenes.The catalyst is a cobalt complex, which is prepared in situ from Co(acac)3, Et2AlCl, and optically active phosphines.Wit
