69094-28-6Relevant academic research and scientific papers
Bis(phenylsulfonyl)methane mediated synthesis of olefins: Via a halogen elimination and double bond migration
Hu, Yanwei,Jiang, Jing,Hu, Ying,Cai, Xin,Wang, Liudi,Chen, Shaohua,Zhang, Shilei,Zhang, Yinan
, p. 2619 - 2622 (2018)
An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination together with double bond migration results in a variety of β,γ-unsaturated bis(phenylsulfonyl)olefins in good yields with only E geometry. The following chemical diversification represents an easy and straightforward access to a series of alkene building blocks.
Hydrogen Bonds involving Polar CH Groups. Part 10. Intramolecular Hydrogen Bonds in 1-(ω-Substituted-alkyl) Bis(phenylsulphonyl)methanes
Li, Chuen,Sammes, Michael P.
, p. 2193 - 2196 (2007/10/02)
Intramolecular hydrogen bonds involving the polar methine group have been detected by 1H n.m.r. spectroscopy in dichloromethane in 1-(ω-methoxyalkyl)- and 1-(ω-dialkylaminoalkyl)-bis(phenylsulphonyl)methanes.Dialkylamino groups are more effective don
