690981-95-4

Upstream product

• 501-53-1 benzyl chloroformate 
• 690981-90-9 3-O-benzyl-1,2-O-isopropylidene-5,6,7,8-tetradeoxy-5-(N-benzyl-N-hydroxyamino)-α-D-gluco-7-eno-octo-1,4-furanose 
• 690981-92-1 3-O-benzyl-1,2-O-isopropylidene-5,6,7,8-tetradeoxy-5-N-(benzylamino)-α-D-gluco-7-eno-octo-1,4-furanose 
• 690981-94-3 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-5-(N-benzyl-N-benzoxycarbonylamino)-α-D-gluco-7-eno-octo-1,4-furanose 

Downstream Products

• 690981-88-5 1,2-O-isopropylidene-5,6,7,8,9-penta-deoxy-5,9-(N-benzoxycarbonyl-imino)-α-D-gluco-nona-1,4-furanose 

Relevant academic research and scientific papers

Synthesis of trihydroxy quinolizidine alkaloids: 1,3-Addition reaction of allylmagnesium bromide to a sugar nitrone

The synthesis of (1R,2R,3S,9aR) and (1R,2R,3S,9aS) trihydroxy quinolizidine alkaloids 3a and 3b from D-glucose derived nitrone 4 is described. The key transformation involves the 1,3-addition of allylmagnesium bromide to nitrone 4 that afforded high diast