690997-44-5Relevant academic research and scientific papers
Dithiafulvenylphosphine as P- and P,S-ligand towards metal carbonyl fragments
Guerro, Michel,Di Piazza, Emmanuel,Jiang, Xin,Roisnel, Thierry,Lorcy, Dominique
, p. 2345 - 2350 (2008/09/21)
The ability of the dithiafulvenylphosphine (P-DTF) to react as a monodentate (P) or a bidentate (P,S) ligand with metal carbonyl complexes such as Mo(CO)6 and MnBr(CO)5 is presented. A series of metal carbonyl complexes are synthesis
Unprecedented metal template effect on the coupling of dithiafulvene moieties
Lorcy, Dominique,Guerro, Michel,Pellon, Pascal,Carlier, Roger
, p. 212 - 213 (2007/10/03)
Coordination of two dithiafulvenyldiphenylphosphines on a Mo(CO) 4 fragment allows a carbon-carbon bond formation upon oxidation, leading to a novel type of metallacycle substituted by a redox active vinylogous tetrathiafulvalene.
