691015-41-5Relevant academic research and scientific papers
Asymmetric 1,4-reductions of hindered β-substituted cycloalkenones using catalytic SEGPHOS-ligated CuH
Lipshutz, Bruce H.,Servesko, Jeff M.,Petersen, Tue B.,Papa, Patrick P.,Lover, Andrew A.
, p. 1273 - 1275 (2007/10/03)
The reagent combination of catalytic amounts of copper hydride ligated by a nonracemic SEGPHOS ligand leads in situ to an extremely reactive species capable of effecting asymmetric hydrosilylations of conjugated cyclic enones in very high ees. An unpreced
