691389-11-4

Upstream product

• 4005-46-3 3-deoxy-1,2-O-isopropylidene-D-glucose 
• 4613-68-7 O¹,O²-isopropylidene-α-D-erythro-3-deoxy-pentodiald-1,4-ose 
• 691389-09-0 [((3aR,5S,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hydroxy-methyl]-phenyl-phosphinic acid methyl ester 

Downstream Products

• 691389-12-5 (3aR,5S,6aR)-2,2-Dimethyl-5-phenylphosphinoylmethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 691389-13-6 (3R,5S)-1-Oxo-1-phenyl-1λ⁵-phosphinane-2,3,5-triol 

Relevant academic research and scientific papers

Synthesis and structure analyses of 1,2,4-tri-O-acetyl-3,5-di-deoxy-5-C- (isopropyl- and phenyl-phosphinyl)-D-erythro-pentopyranoses

1H NMR spectroscopy for phosphorus containing hetero sugars (phospha sugars 9a-d and 17a-d) revealed the stereoisomeric configurations and the chair conformations for α - and β -1,2,4-tri-O-acetyl-3,5-di- deoxy-5-C-(isopropyl- and phenyl-phosphinyl)-D-erythro-pentopyranoses. The conformations of the title compounds were characterized as 4C 1 chair form in CDCl3 by 1H NMR (500 MHz), and the conformations were in accord with those in the solid state determined by X-ray crystallographic analyses.