69225-80-5Relevant academic research and scientific papers
Chemo- and regioselective reductive deoxygenation of 1-en-4-yn-ols into 1,4-enynes through FeF3 and TfOH co-catalysis
Yang, Zonglian,Kumar, Rapolu Kiran,Liao, Peiqiu,Liu, Zhaohong,Li, Xingqi,Bi, Xihe
supporting information, p. 5936 - 5939 (2016/05/24)
We report chemo- and regioselective direct reductive deoxygenation of 1-en-4-yn-3-ols into 1,4-enynes through FeF3 and TfOH cooperative catalysis under NBSH-mediated conditions. Further, we show the efficient synthesis of a pharmaceutically significant 1,4-enyne. The present methodology can also be used for chemo- and regioselective direct deoxygenation of other alcohols.
Synthesis of substituted naphthalenes and carbazoles by the palladium-catalyzed annulation of internal alkynes
Huang, Qinhua,Larock, Richard C.
, p. 7342 - 7349 (2007/10/03)
An efficient synthesis of highly substituted naphthalenes has been developed by the palladium-catalyzed annulation of a variety of internal alkynes, in which two new carbon-carbon bonds are formed in a single step under relatively mild reaction conditions
