69274-93-7

Upstream product

• 69274-86-8 (S)-(+)-4-methylhex-5-enoic acid 
• 67214-57-7 (R)-(-)-7-Oxo-4-methyl-heptansaeure-methylester 
• 69274-84-6 methyl (S)-6-(o-nitrophenylseleno)-4-methylhexanoate 
• 69274-83-5 (R)-(+)-4-methylheptanedioic acid monomethyl ester 
• 69308-75-4 methyl (S)-(+)-6-bromo-4-methylhexanoate 
• 401916-29-8 (6S,3RS)-2,6-dimethyl-7-octene-2,3-diol 
• 69274-92-6 (S)-(+)-5-methylhex-5-en-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 331810-40-3 (S)-5-tosyloxypebt-2-yl acetate 
• 79016-01-6 (3S,11S)-29-benzyloxy-3,11-dimethylnonacos-14-yn-2-one 
• 79015-99-9 (3S,11R)-29-benzyloxy-3,11-dimethylnonacos-14-yn-2-one 
• 79015-96-6 (3S,11S)-(+)-29-benzyloxy-3,11-dimethylnonacos-1-en-14-yne 
• 79015-94-4 (3S,11R)-(+)-29-benzyloxy-3,11-dimethylnonacos-1-en-14-yne 
• 79015-98-8 (3S,11S)-29-benzyloxy-3,11-dimethylnonacos-14-yn-2-ol 
• 79015-98-8 (3S,11R)-29-benzyloxy-3,11-dimethylnonacos-14-yn-2-ol 
• 544-76-3 Hexadecane 

Relevant academic research and scientific papers

Synthesis of all the six components of the female-produced contact sex pheromone of the German cockroach, Blattella germanica (L.)

All of the following six components of the female sex pheromone of the German cockroach, Blattella germanica (L.) were synthesized: (3S,11S)-3,11-dimethyl-2-nonacosanone (1), its 29-hydroxy derivative 2, its 29-oxo derivative 3, (3S,11S)-3,11-dimethyl-2-heptacosanone (4), its 27-hydroxy derivative 5, and its 27-oxo derivative 6. Both the enantiomers of citronellal were employed as the chiral sources and Wacker oxidation was employed for the introduction of the carbonyl group at C-2.