692749-35-2

Upstream product

• 727985-23-1 (E)-(3S,4S,7R)-4-(tert-Butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-8-(4-methoxy-benzyloxy)-5,7-dimethyl-oct-5-ene-1,2-diol 
• 692749-41-0 (S)-3-[(E)-(2S,3S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-4,6-dimethyl-2-vinyl-hept-4-enoyl]-4-isopropyl-oxazolidin-2-one 
• 692749-34-1 1-[(E)-(2R,5S,6R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-2,4-dimethyl-octa-3,7-dienyloxymethyl]-4-methoxy-benzene 
• 692749-33-0 (S)-3-[(E)-(2S,3S,6R)-3-Hydroxy-7-(4-methoxy-benzyloxy)-4,6-dimethyl-2-vinyl-hept-4-enoyl]-4-isopropyl-oxazolidin-2-one 
• 220213-54-7 (E)-(R)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-pent-2-en-1-ol 
• 692749-42-1 (E)-(2R,3S,6R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(tert-butyl-dimethyl-silanyloxymethyl)-7-(4-methoxy-benzyloxy)-4,6-dimethyl-hept-4-enal 

Downstream Products

• 692749-37-4 (E)-(2S,3R,4S,5S,8R)-1,5-Bis-(tert-butyl-dimethyl-silanyloxy)-4-(tert-butyl-dimethyl-silanyloxymethyl)-2-(3-ethyl-4,5-dihydro-isoxazol-5-yl)-9-(4-methoxy-benzyloxy)-6,8-dimethyl-non-6-en-3-ol 
• 692749-36-3 (E)-(3S,4R,5S,6S,9R)-6-(tert-Butyl-dimethyl-silanyloxy)-3,5-bis-(tert-butyl-dimethyl-silanyloxymethyl)-10-(4-methoxy-benzyloxy)-7,9-dimethyl-deca-1,7-dien-4-ol 

Relevant academic research and scientific papers

Total synthesis and stereochemical assignment of myriaporones 1, 3, and 4

Two stereoselective aldol reactions, a nitrile oxide cycloaddition, and a stereoselective late-stage epoxidation were key steps in the total synthesis of myriaporones 1, 3, and 4 (see scheme). The synthesis allowed the unambiguous assignment of stereogeni