692782-19-7Relevant articles and documents
Retention of configuration and regiochemistry in allylic alkylations via the memory effect
Faller,Sarantopoulos, Nikos
, p. 2179 - 2185 (2004)
The results of a systematic variation of achiral monodentate ligands used for the Pdcatalyzed alkylation of crotyl and 3-buten-2-yl acetates and carbonates are presented. A significant degree of retention of regiochemistry and stereochemistry was observed for these substrates, especially for nonracemic 3-buten-2-yl ethyl carbonate with PCyxPhs-x and carbene ligands.