6928-73-0

Upstream product

• 7439-95-4 magnesium 
• 103-63-9 1-phenyl-2-bromoethane 

Downstream Products

• 799267-42-8 (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)FeCHMePh 
• 799267-49-5 (2,4-bis(2,6-diisopropylphenylimino)pent-3-yl)Fe(phenethyl) 
• 1196586-81-8 [Ni(Me)(C₂H₄Ph)(1,2-bis(diisopropylphosphino)ethane)] 
• 1196586-84-1 [Ni(Me)(CH(Me)Ph)(1,2-bis(diisopropylphosphino)ethane)] 
• 1352558-62-3 4,4-bis(2-phenylethyl)-1-triisopropylsilyl-1,4-dihydropyridine 
• 1196586-82-9 [Ni(1,2-bis(di-isopropylphosphino)ethane)(η²-C,C-styrene)] 

Relevant academic research and scientific papers

Symmetric diarylsulfoxides as asymmetric sulfinylating reagents for dialkylmagnesium compounds

At -78 °C, primary dialkylmagnesium compounds reacted with diarylsulfoxides when 1.5 equiv of the dilithium salt of (S)-BINOL was added as a promotor. Alkyl aryl sulfoxides resulted in up to quantitative yield and with up to 97% ee. This demonstrates the feasibility of asymmetric sulfinylations by achiral sulfinylating agents (from the perspective of Alkyl2Mg) as well as the feasibility of asymmetric sulfoxide-magnesium exchanges (from the perspective of Ar2SO).