69300-14-7

Basic information

• Product Name: 3-Cyclododecylpropanenitrile
• Synonyms: 3-Cyclododecylpropanenitrile;Cyclododecanepropanenitrile
• CAS NO: 69300-14-7
• Molecular Formula: C₁₅H₂₇N
• Molecular Weight: 0
• Mol File: 69300-14-7.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cyclododecylpropanenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclododecylpropanenitrile(69300-14-7)
• EPA Substance Registry System: 3-Cyclododecylpropanenitrile(69300-14-7)

Safety Data

• Hazardous Substances Data: 69300-14-7(Hazardous Substances Data)

Upstream product

• 69300-20-5 (Z)-Cyclododec-1-enecarbonitrile 
• 69300-13-6 cyclododecanecarbonitrile 
• 93190-53-5 Cyclododecyl-acetic acid ethyl ester 
• 830-13-7 cyclododecanone 
• 70755-01-0 2-hydroxyethylcyclododecane 
• 1903-26-0 cyclododecylideneacetic acid ethyl ester 
• 61682-10-8 cyclododecyl iodide 
• 107-13-1 acrylonitrile 
• 294-62-2 cyclododecane 
• 71-43-2 benzene 
• 143-33-9 sodium cyanide 
• 146449-46-9 (2-Bromo-ethyl)-cyclododecane 
• 2537-48-6 diethyl 1-cyanomethylphosphonate 
• 5037-22-9 formyl cyclododecane 

Downstream Products

• 146449-40-3 7-Chloro-2-[2-(4-methyl-cyclohexyl)-ethyl]-6-nitro-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one 
• 146449-27-6 7-Hydroxy-2-[2-(4-methyl-cyclohexyl)-ethyl]-6-nitro-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one 
• 118314-10-6 7-Amino-2-[2-(4-methyl-cyclohexyl)-ethyl]-6-nitro-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one 
• 146449-15-2 7-Hydroxy-2-[2-(4-methyl-cyclohexyl)-ethyl]-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one 
• 118313-97-6 5-(2-Cyclododecyl-ethyl)-[1,3,4]thiadiazol-2-ylamine 
• 118313-98-7 5-[2-(4-Methyl-cyclohexyl)-ethyl]-[1,3,4]thiadiazol-2-ylamine 
• 22047-01-4 3-Cyclododecyl-propionaldehyde 

Relevant articles and documents

Indium(III) acetate-catalyzed intermolecular radical addition of organic iodides to electron-deficient alkenes

In the presence of phenylsilane and a catalytic amount of indium(III) acetate, organic iodides added to electron-deficient alkenes in ethanol at room temperature. Both simple and functionalized organic iodides were applicable to this reaction. A plausible reaction mechanism involves the formation of indium hydride species by hydride transfer from silicon to indium and an indium hydride-mediated radical chain process.

Hydrocarbon activation. Synthesis of β-cycloalkyl (Di)nitriles through photosensitized conjugate radical addition

Photoinduced hydrogen abstraction from aliphatic cyclic hydrocarbons (C5 to C7, C12, as well as adamantane) by triplet aromatic ketones in the presence of α,β-unsaturated (di)nitriles offers a straightforward entry to the corresponding alkylated (di)nitriles via the alkyl radicals. Yields are moderate to good depending on the olefins structure (substitution in β slows down the addition to mononitriles, but with α,α-dinitriles electronic activation allows efficient alkylation also of β,β-disubstituted substrates). A tandem alkylation - cyclization process has been obtained with (1-methylpent-4-enylidene)malononitrile.

Cob(I)alamine as catalyst. I. Communication. Reduction of saturated nitriles in aqueous solution

-