693221-75-9

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 135362-69-5 3-(4-methoxybenzyl)oxypropan-1-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 128461-65-4 3-(p-methoxybenzyloxy)propanal 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 693221-74-8 (S)-tert-butyl ((1-(4-methoxybenzyloxy)-4,4-dimethylhex-5-en-3-yl)oxy)dimethylsilane 
• 693221-73-7 (3S)-1-p-methoxybenzyloxy-4,4-dimethylhex-5-en-3-ol 
• 869801-36-5 1-tert-butyldimethylsilyloxy-4,4-dimethylhex-5-en-3-one 
• 869801-23-0 (+/-)-1-tert-butyldimethylsilyloxy-4,4-dimethylhex-5-en-3-ol 
• 869801-25-2 (3S)-4,4-dimethylhex-5-ene-1,3-diol 
• 869801-24-1 1-hydroxy-4,4-dimethylhex-5-en-3-one 
• 925-90-6 ethylmagnesium bromide 
• 472979-36-5 (3S)-3-tert-butyldimethylsilyloxy-5-p-methoxybenzyloxy-2,2-dimethylpentanal 

Relevant academic research and scientific papers

Studies towards the synthesis of epothilone A via organoboranes

Studies towards the synthesis of epothilone A via organoboranes have been described. A modified procedure for the large-scale preparation of B-γ,γ-dimethylallyldiisopinocampheylborane from prenyl alcohol has been developed. This reagent, upon reaction wit

Preparative-scale synthesis of both antipodes of B-γ,γ- dimethylallyldiisopinocampheylborane: Application for the synthesis of C 1-C6 subunit of epothilone

A preparative-scale synthesis of B-γ,γ- dimethylallyldiisopinocampheylborane starting from prenyl alcohol has been described. This reagent, upon reaction with various aldehydes, provides the corresponding α,α-dimethylhomoallylic alcohols in high enantiose