693783-08-3

Basic information

• Product Name: (4R)-4-[(1S)-1-(tert-butyldimethylsiloxy)-2-methyl]propyl-6-phenyl-8-trimethylsilyl-(Z)-1,5-octadien-7-yne
• Synonyms: (4R)-4-[(1S)-1-(tert-butyldimethylsiloxy)-2-methyl]propyl-6-phenyl-8-trimethylsilyl-(Z)-1,5-octadien-7-yne
• CAS NO: 693783-08-3
• Molecular Weight: 440.817
• Mol File: 693783-08-3.mol

Chemical Properties

• CAS DataBase Reference: (4R)-4-[(1S)-1-(tert-butyldimethylsiloxy)-2-methyl]propyl-6-phenyl-8-trimethylsilyl-(Z)-1,5-octadien-7-yne(CAS DataBase Reference)
• NIST Chemistry Reference: (4R)-4-[(1S)-1-(tert-butyldimethylsiloxy)-2-methyl]propyl-6-phenyl-8-trimethylsilyl-(Z)-1,5-octadien-7-yne(693783-08-3)
• EPA Substance Registry System: (4R)-4-[(1S)-1-(tert-butyldimethylsiloxy)-2-methyl]propyl-6-phenyl-8-trimethylsilyl-(Z)-1,5-octadien-7-yne(693783-08-3)

Safety Data

• Hazardous Substances Data: 693783-08-3(Hazardous Substances Data)

Upstream product

• 762-72-1 allyl-trimethyl-silane 
• 693782-95-5 (6S)-6-O-tert-butyldimethylsilyl-3-O-trimethylsilyl-7-methyl-3-phenyl-1-trimethylsilyl-(4E)-octen-1-yne-3,6-diol 
• 693782-99-9 (6S)-6-O-tert-butyldimethylsilyl-7-methyl-3-O-trimethylsilyl-1-trimethylsilyl-3-phenyl-(4E)-octen-1-yne-3,6-diol 

Relevant articles and documents

Diastereoselective allylations of allyl-propargyl hybrid cations: Synthesis of conjugated 1,5-dien-7-yne frameworks bearing C(4)-stereogenic centers

Chiral C(4)-substituted (E)- or (Z)-1-alkynyl-1-trimethylsilyloxy-2-butene systems provide anti-(Z) or syn-(Z) conjugated dienyne, with a very high level of stereocontrol, on treatment with BF3·OEt2 in CH2Cl2 at