6941-20-4Relevant academic research and scientific papers
Two new phosphinic amides: Synthesis, crystal structure, and theoretical study of hydrogen bonding
Hamzehee, Farahnaz,Pourayoubi, Mehrdad,Farhadipour, Abolghasem,Choquesillo-Lazarte, Duane
, p. 359 - 367 (2017)
Two novel phosphinic amides, (C6H5)2P(O)(NH?cyclo?C7H13) (I) and (C6H5)2P(O)(NH?cyclo?C6H11) (II) were synthesized and characterized by spectrosc
Synthesis, characterization and biological evaluation of a nanorod five-coordinated Sn(IV) complex. Theoretical studies of (CH3)2Sn(O2PPh2)2
Dorosti, Niloufar,Mohammadpour, Hadis
, (2018)
A new five-coordinated diorganotin(IV) complex with formula Sn(CH3)2Cl2L (L?=?(C6H5)2(O)P(NHC6H11)), with a rod-shaped nanostructure, was synthesized using a sonochemi
Copper(II)-Photocatalyzed N-H Alkylation with Alkanes
Donabauer, Karsten,K?nig, Burkhard,Narobe, Rok,Yakubov, Shahboz,Zheng, Yi-Wen
, p. 8582 - 8589 (2020/09/23)
We report a practical method for the alkylation of N-H bonds with alkanes using a photoinduced copper(II) peroxide catalytic system. Upon light irradiation, the peroxide serves as a hydrogen atom transfer reagent to activate stable C(sp3)-H bonds for the reaction with a broad range of nitrogen nucleophiles. The method enables the chemoselective alkylation of amides and is utilized for the late-stage functionalization of N-H bond containing pharmaceuticals with good to excellent yields. The mechanism of the reaction was preliminarily investigated by radical trapping experiments and spectroscopic methods.
Copper-Catalyzed Oxidative Alkylation (Methylation) of Phosphonamides and Phosphinamides Using Dicumyl Peroxide
Xiao, Jing,Su, Qiong,Dong, Wanrong,Peng, Zhihong,Zhang, Yingjun,An, Delie
, p. 9497 - 9504 (2017/09/23)
An effective and practical CuI-catalyzed methodology toward N-alkyl or N-methyl phosphonamides and phosphinamides was herein demonstrated. The transformation took place readily under the oxidative conditions, and plenty of N-alkylated (methylated) amides
SOME NEW PHOSPHINIC AMIDES R2P(O)NHR'
Brueck, A.,Kuchen, W.,Peters, W.
, p. 129 - 134 (2007/10/03)
P,P-Diorganylphosphinic amides R2P(O)NHR' (R = tBu, iPr, Ph; R' = Et, Pr, Cy, iPr, tBu, Ph, etc.) have been prepared by reaction of R2PCl with the corresponding lithiated amine followed by oxidation with H2O2.Th
