694457-63-1Relevant academic research and scientific papers
Efficient synthesis of (±)-γ-lycorane employing stereoselective conjugate addition to nitroolefin
Yasuhara, Tomohisa,Osafune, Emi,Nishimura, Katsumi,Yamashita, Mitsuaki,Yamada, Ken-Ichi,Muraoka, Osamu,Tomioka, Kiyoshi
, p. 3043 - 3045 (2004)
(±)-γ-Lycorane 3 was synthesized in 52% overall yield via seven steps from 5 by employing the highly stereoselective nitro-Michael cyclization of 5 to 9 and diastereoselective conjugate addition of aryllithium to a nitroolefin 10 as two key steps.
