694464-69-2Relevant academic research and scientific papers
Enantioselective reduction of ketones and imines catalyzed by (CN-Box)ReV-oxo complexes
Nolin, Kristine A.,Ahn, Richard W.,Kobayashi, Yusuke,Kennedy-Smith, Joshua J.,Toste, F. Dean
supporting information; experimental part, p. 9555 - 9562 (2010/10/03)
The development and application of chiral, non-racemic ReV-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.
