69447-98-9

Upstream product

• 78002-58-1 (chloro-2hydroxy-3cyclohexenyl-4)acetate de methyle-cis 
• 78002-47-8 ((1R,2R,5S)-6,6-Dichloro-bicyclo[3.1.0]hex-2-yl)-acetic acid 
• 20006-86-4 (cyclopentenyl-3)acetate de methyle 
• 78002-47-8 acides(dichloro-6,6-bicyclo<3.1.0>hexyl-2)acetiques 
• 78002-45-6 (dichloro-6,6 bicyclo<3.1.0>hexyl-2)acetates de methyle 

Downstream Products

• 69448-02-8 (dichloro-2,3cyclohexenyl-4)acete de methyle 
• 78002-63-8 ((1S,4S)-3-Chloro-4-hydroxy-cyclohex-2-enyl)-acetic acid 
• 78002-62-7 ((1R,2S)-3-Chloro-2-hydroxy-cyclohex-3-enyl)-acetic acid 
• 78002-62-7 ((1S,2S)-3-Chloro-2-hydroxy-cyclohex-3-enyl)-acetic acid 

Relevant academic research and scientific papers

Ouverture de dichlorocyclopropanes en presence d'un nucleophile interne. Absence de participation intramoleculaire. Rearrangement concerte en chlorures allyliques

It is shown that a conveniently placed internal nucleophile (carboxyl group) is not involved with the rearrangement of a diclorocyclopropane into an allylic chloride.This result appears to support a concerted mechanism of a ?s2 + ?a2 type for this rearrangement.In the products obtained, the allylic chloride may undergo displacement either by solvent (H2O), leading to alcohols, or by the internal carboxyl group, leading to a lactone.