69468-56-0Relevant academic research and scientific papers
Studies on Unstabilized ?-Sulfuranes: Synthesis of trans-1,2-Disubstituted Epoxides
Tewari, R. S.,Awasthi, A. K.,Chaturvedi, S. C.
, p. 1565 - 1568 (2007/10/02)
4-Nitrobenzylidenedimethylsulfurane, a semi-stabilized sulfonium ylide has been generated by the attack of methylsulfinyl carbanion in dimethylsulfoxide and reacted with a series of substituted benzaldehydes, furfural and benzylideneacetophenone to afford trans-1,2-disubstituted epoxides in fair to good yields.The structural assignments of the products are based on IR and NMR spectral evidences. - Keywords: 4-Nitrobenzylidenedimethylsulfurane
