69471-13-2Relevant academic research and scientific papers
REACTIONS OF (ARENE)TRICARBONYLCHROMIUM STABILIZED CARBOCATIONS WITH AROMATICS AND β-DICARBONYL COMPOUNDS
Uemura, Motokazu,Minami, Tatsuya,Hayashi, Yuji
, p. 119 - 126 (2007/10/02)
Primary and secondary benzylic carbocations, stabilized by a tricarbonylchromium group, gave coupling products with several aromatics or β-dicarbonyl compounds in good yield and this reaction presents a new synthetic method for carbon-carbon bond formation.The chromium complexes of tertiary benzyl alcohols gave dehydrated products without carbon-carbon coupling products under similar conditions.
