69485-57-0

Basic information

• Product Name: (E/Z)-1-(Trimethylsilyl)-5-phenylpent-2-ene
• Synonyms: (E/Z)-1-(Trimethylsilyl)-5-phenylpent-2-ene
• CAS NO: 69485-57-0
• Molecular Weight: 218.414
• Mol File: 69485-57-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E/Z)-1-(Trimethylsilyl)-5-phenylpent-2-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (E/Z)-1-(Trimethylsilyl)-5-phenylpent-2-ene(69485-57-0)
• EPA Substance Registry System: (E/Z)-1-(Trimethylsilyl)-5-phenylpent-2-ene(69485-57-0)

Safety Data

• Hazardous Substances Data: 69485-57-0(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 63922-69-0 (2-trimethylsilylethylidene)triphenylphosphorane 
• 123159-55-7 <2-(trimethylsilyl)ethyl>tris(2-methylphenyl)phosphonium iodide 
• 119220-57-4 5-phenyl-1-trimethylsilyl-3-pentanone 
• 144487-95-6 [1-Phenethyl-3-trimethylsilanyl-prop-(E)-ylidene]-(2-phenyl-aziridin-1-yl)-amine 

Downstream Products

• 1150593-22-8 (E)-2-(6-phenyl-1-trifluoromethyl-3-hexenylidene)-1,3-dithiane 

Relevant articles and documents

Silicon-directed Bamford-Stevens Reaction of β-Trimethylsilyl N-Aziridinylimines

The Me3Si group in β-trimethylsilyl N-aziridinylimines is able to direct the Bamford-Stevens reaction with or without rhodium acetate as catalyst to give allylic silanes as major or exclusive products.

UNUSUAL REACTION OF 2-TRIMETHYLSILYLETHYLIDENETRIARYLPHOSPHORANES (SEYFERTH-WITTIG REAGENT) WITH α-METHYLALDEHYDES: A NOVEL METHOD FOR HIGHLY CRAM-DIASTEREOSELECTIVE ADDITION OF VINYL ANION EQUIVALENT

By the reaction of α-methylaldehydes with trimethylsilylethylidenetriarylphosphoranes the introduction of vinyl group is effected in highly Cram-selective manner.