695-05-6

Usage

Uses

Used in Fragrance and Flavor Industry:
TRICYCLO[2.2.1.0(2,6)]HEPTAN-3-ONE is used as a fragrance and flavoring agent for its woody, floral scent, enhancing the sensory experience of various products.
Used in Pest Management:
In the field of pest management, TRICYCLO[2.2.1.0(2,6)]HEPTAN-3-ONE is used as a pheromone to disrupt the mating behavior of bark beetles, serving as an eco-friendly approach to controlling these pests.
Used in Pharmaceutical Industry:
TRICYCLO[2.2.1.0(2,6)]HEPTAN-3-ONE is utilized in the pharmaceutical industry for its potential applications due to its biological activities, such as antioxidant and antimicrobial properties, offering benefits in the development of new medications.

InChI:InChI=1/C7H8O/c8-7-3-1-4-5(2-3)6(4)7/h3-6H,1-2H2

Upstream product

• 38996-39-3 bicyclo<2.2.1>hept-5-en-2-one p-toluenesulfonylhydrazone 
• 24271-57-6 2-exo-aminonorbornan-3-one hydrochloride 
• 5169-59-5 2-diazonorbornan-3-one 

Downstream Products

• 28253-04-5 2-Methyl-3-phenylsulfanyl-bicyclo[2.2.1]hept-2-ene 
• 93045-13-7 Nortricyclanon-azin 
• 1777-45-3 cis-Bicyclo <3.1.0> hexan-3-carbonsaeure 
• 13388-51-7 bicyclo[3.1.0]hexane-3-carboxylic acid 
• 52883-21-3 3-Cyclohexyl-nortricyclen 
• 20238-40-8 (1S,2S,4R)-1-Bicyclo[2.2.1]hept-2-yl-pyrrolidine 
• 5649-99-0 4-oxatricyclo[3.2.1.0^2,7]octan-3-one 
• 4396-25-2 3-azatricyclo[3.2.1.0^2,7]octan-4-one 
• 55408-76-9 3-(p-Methoxyphenyl)-3-nortricyclanol 
• 7116-30-5 3-Phenyl-3-nortricyclyl-Kation 
• 55408-78-1 3-(m,m'-Trifluormethyl-phenyl)-3-nortricyclanol 
• 55408-77-0 3-(p-Trifluormethyl-phenyl)-3-nortricyclanol 
• 64178-08-1 3-Cyclohexyl-nortricyclan-3-ol 

Relevant academic research and scientific papers

Protonated cyclopropanes in α-aminoketone deamination

Deamination of 2-amino-4,4-dideuterio-6,6-dimethylcyclohexanone, 2-exo-amino- and 2-endo-amino-norbornane-3-one, 2-diazo-norbornan-3-one, 2-exo-amino-5,6-exo-dideuterionorbornan-3-one and the corresponding 5,6-endo-dideuterio isomer has been studied.The nature of the products, the deuterium location in them, and the high retention of steric identity in the carbocations are interpreted in terms of ?-bond participation leading to corner- and edge-protonated cyclopropanes as reaction intermediates.Results with other destabilized carbocations are correlated.

Deamination Reactions. 35. Decomposition of 5-Norbornene-2-diazonium Ions. Derivatives of Bicyclohept-2-ene

Photolysis of 5-norbornen-2-one tosylhydrazone (4) in aqueous sodium hydroxide afforded 4percent of 3-norpinen-2-ol (3) in addition to 5-norbornen-2-ol (5, 10percent) and nortricyclanol (6, 86percent). 3 arises from 5-norbornene-2endo-diazonium ions (2) as shown by the nitrous acid deamination of the epimeric amines 1 and 7. 3-Norpinen-2-one (12) was isolated by oxidation of the deamination products followed by preparative g.l.c. 3 and 12 were synthesized independently from norpinan-2-one (9) via sulfenylation and sulfoxide pyrolysis.The norbornene -> norpinene rearrangement is slightly enhanced by 1-OCH3.The deamination of 1-methoxy-5-norbornen-2endo-amine (14) produced 10percent of 12, as compared to 5.6percent of 3 from 1.