695-89-6

Upstream product

• 82126-24-7 C₉H₁₀N₂ 
• 63904-59-6 (t-3a,t-4a,t-8a,t-9a)-3a,4,4a,5,8,8a,9,9a-Octahydro-r-4,c-9-azo-t-5,t-8-methano-1H-cyclopentanaphthalin 

Downstream Products

• 95-13-6 1-indene 
• 300-57-2 allylbenzene 

Relevant academic research and scientific papers

Azo Bridges from Azines, III. Unexpected Formation of a Compound with Parallel C = C and N = N Bonds

Dialdehyde 5 reacts with hydrazine at pH > 7 to form the trimeric azine 6Tr, at pH 4, however, to yield unexpectedly 8, which contains parallel C = C and N = N bonds in close proximity.The complex reaction is clarified. 8 is characterized by structure proving reactions and its spectroscopic data.

THERMAL REACTION OF 2,3-DIAZATETRACYCLO4,11.06,8>UNDECA-2,9-DIENES: THE NITROGEN EXTRUSION AND THE MASKED HOMODIENYL-1,5-HYDROGEN SHIFT

Thermolyses of the title compounds produce three kinds of products which are derived from nitrogen extrusion and 1,5-hydrogen shifts.The reaction mechanism is discussed in connection with the thermal behavior of bicyclononatriene.