69519-69-3Relevant academic research and scientific papers
Rearrangement of alkynyl sulfoxides catalyzed by gold(I) complexes
Shapiro, Nathan D.,Toste, F. Dean
, p. 4160 - 4161 (2008/02/01)
A series of gold(I)-catalyzed rearrangement reactions of alkynyl sulfoxides are reported. Homopropargylsulfoxides are rearranged to benzothiepinones or benzothiopines, while α-thioenones are formed in the reaction of propargylsulfoxides. The proposed mech
α-CETOALDEHYDES A GROUPEMENT ALDEHYDIQUE OU CETONIQUE PROTEGE
Duhamel, Lucette,Chauvin, Joe,Messier, Angela
, p. 4171 - 4174 (2007/10/02)
α-Ketoaldehydes with protected ketogroup 2 or protected aldehydrogroup 3 are obtained by reaction of thiophenol or methanol with α-chloro-α-(phenylthio)aldehydes 7.
