69682-07-1Relevant academic research and scientific papers
A mechanistic study of the photoreaction of dimethylaniline and methyl chloroacetate. Role of acid-base properties in both the ground state and the excited state
Numao, Naganori,Hamada, Tatsuo,Yonemitsu, Osamu
, p. 1889 - 1892 (2007/10/13)
On irradiation, dimethylaniline 1 reacted with methyl chloroacetate 2 in both acidic and basic solutions to yield methyl o- and p-dimethylaminophenylacetates (3a,3b). Kinetic treatments on the basis of quantum yields for fluorescence quenching and disappearance of 1 revealed the mechanism, which involves the exciplex in a broad sense under acidic conditions and both the exciplex and the charge-transfer complex under basic conditions.
