697302-71-9Relevant academic research and scientific papers
Total synthesis of 1-O-methyllateriflorone
Nicolaou,Sasmal, Pradip K.,Xu, Hao,Namoto, Kenji,Ritzen, Andreas
, p. 4225 - 4229 (2003)
The unique spiroxalactone framework of lateriflorone (1) consists of a prenylated dihydrobenzoquinone moiety and a trioxatetracyclotetradecane system. A tandem Claisen rearrangement/Diels-Alder cascade was the key step in the synthesis of the complex tetr
Biomimetically Inspired Total Synthesis and Structure Activity Relationships of 1-O-Methyllateriflorone. 6π Electrocyclizations in Organic Synthesis
Nicolaou,Sasmal, Pradip K.,Xu, Hao
, p. 5493 - 5501 (2007/10/03)
The total synthesis of 1-O-methyllateriflorone (2) is described. The construction of the cage-like domain of the molecule involved a biomimetic Claisen/Diels-Alder cascade, whereas the novel spiroxalactone framework was generated by an intramolecular Mich
